Flexible Piezoelectric Tactile Sensor With Cilia-Inspired Structures Based on Electrospun PVDF/Fe₃O₄ Nanofibers

摘要

Flexible tactile sensors have promising applications at the field of intelligent robotics. However, manufacturing flexible tactile sensors with excellent stability and high sensitivity remain a great challenge. In the present work, polyvinylidene fluoride (PVDF)-based nanofibers are prepared by electrospinning loaded with Fe3O4 nanoparticles (NPs). X-ray diffraction (XRD) and attenuated total reflection Fourier transform infrared spectroscope (ATR-FTIR) results indicate that the addition of Fe3O4 NPs promotes the generation of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -phase in PVDF polymer, which greatly improves piezoelectric properties of composite nanofibers. Simultaneously, a flexible piezoelectric tactile sensor with cilia-inspired structures (PTSCS) based on PVDF/Fe3O4 nanofibers is proposed, which consists of the substrate with cilia structures, Ag electrodes, composite nanofiber membrane, and nanofiber protective layer. The PTSCS demonstrates a higher output voltage compared to sensors with bump and planar structures, which also exhibits high robustness, with a stable output after 30000 cycles of vibration testing. More importantly, the PTSCS demonstrates superior performance in recognizing surface texture and temperature of objects. The flexible PTSCS has potential use in areas such as intelligent soft robotics and material recognition.