Extreme Toughening of Soft Materials with Liquid Metal

Abstract

Abstract Soft and tough materials are critical for engineering applications in medical devices, stretchable and wearable electronics, and soft robotics. Toughness in synthetic materials is mostly accomplished by increasing energy dissipation near the crack tip with various energy dissipation techniques. However, bio‐materials exhibit extreme toughness by combining multi‐scale energy dissipation with the ability to deflect and blunt an advancing crack tip. Here, we demonstrate a synthetic materials architecture that also exhibits multi‐modal toughening, whereby embedding a suspension of micron sized and highly deformable liquid metal (LM) droplets inside a soft elastomer, the fracture energy dramatically increases by up to 50x (from 250 ± 50 J m ‐2 to 11,900 ± 2600 J m ‐2 ) over an unfilled polymer. For some LM‐embedded elastomer (LMEE) compositions, the toughness is measured to be 33,500 ± 4300 J m ‐2 , which far exceeds the highest value previously reported for a soft elastic material. This extreme toughening is achieved by (i) increasing energy dissipation, (ii) adaptive crack movement, and (iii) effective elimination of the crack tip. Such properties arise from the deformability of the LM inclusions during loading, providing a new mechanism to not only prevent crack initiation, but also resist the propagation of existing tears for ultra tough, soft materials.