Reconfiguring flexibility in renewable power-to-ammonia systems using molten-salt thermal energy storage in the ammonia synthesis loop: A coordinated electro-hydrogen-thermal scheduling approach

Abstract

In renewable power-to-ammonia (ReP2A) systems, the intermittency of wind and solar generation propagates through electrolytic hydrogen production and induces thermal instability in the ammonia synthesis reactor (ASR). The resulting temperature cycling accelerates fatigue and shortens service life, while reactor thermal inertia limits flexible start-up, shutdown, and load adjustment. To address this issue, this study integrates molten-salt thermal energy storage (MS-TES) into the Haber-Bosch synthesis loop and develops a coordinated electro-hydrogen-thermal scheduling framework. MS-TES decouples hydrogen supply fluctuations from reactor thermal dynamics by enabling hot standby operation and sustained thermal support during start-up and low-load conditions. A state-space model is established to capture the thermal dynamics of the ASR and MS-TES. Based on this model, an optimal scheduling program coordinates ammonia synthesis operation with hydrogen production, battery energy storage (BES), and hydrogen storage (HS). The problem is formulated as a mixed-integer linear program (MILP) and extended with information gap decision theory (IGDT) to address renewable uncertainty. Case studies based on an industrial-scale project in northern China show that MS-TES enhances reactor thermal stability and system-level flexibility, while diminishing the marginal benefit of large BES capacity. As a result, a configuration combining small BES, HS, and MS-TES achieves near-equivalent performance to large-BES systems, with lower investment and improved economic returns. Year-round simulations further show that MS-TES avoids ASR start-up and shutdown and delivers consistently higher net revenue under variable renewable conditions.